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・ Chlorinated polyvinyl chloride
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Chlorine pentafluoride
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Chlorine pentafluoride : ウィキペディア英語版
Chlorine pentafluoride

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Chlorine pentafluoride is an interhalogen compound with formula ClF5. This colourless gas is an strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C4v symmetry, as confirmed by its high resolution 19F NMR spectrum.
==Preparation==
Some of the earliest research on the preparation was classified. It was first prepared by fluorination of chlorine trifluoride at high temperatures and high pressures:
:ClF3 + F2 → ClF5
NiF2 catalyzes this reaction.
Certain metal fluorides, MClF4 (i.e. KClF4, RbClF4, CsClF4) react with F2 to produce ClF5 and the corresponding alkali metal fluoride.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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